When you buy an ESP-01 module from local market you might not find datasheet and pin out for the same. Fortunately for ESP8266, there is a huge community which helps but that is not the case with many devices. Here is the pinout of the ESP-01 module,
Remember that the VCC supported is 3.3V. so, if you are connecting a Host board with 5V output, you need to have a level translator. The TXD and RXD pins are used to connect to the host controller board.
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